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Issue 26, 2013
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Activation of CO2 by phosphinoamide hafnium complexes

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Abstract

Hf–phosphinoamide cation complexes behave as metal-based frustrated Lewis pairs and bind one or two equivalent of CO2 and in as well can activate CO2 in a bimetallic fashion to give a pseudo-tetrahedral P2CO2 fragment linking two Hf centres.

Graphical abstract: Activation of CO2 by phosphinoamide hafnium complexes

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Publication details

The article was received on 17 Nov 2012, accepted on 27 Jan 2013 and first published on 05 Feb 2013


Article type: Communication
DOI: 10.1039/C3CC38286A
Citation: Chem. Commun., 2013,49, 2610-2612
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    Activation of CO2 by phosphinoamide hafnium complexes

    M. J. Sgro and D. W. Stephan, Chem. Commun., 2013, 49, 2610
    DOI: 10.1039/C3CC38286A

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