Issue 18, 2013
From the journal:

Chemical Communications

Molecular evidence for the intermolecular S⋯S interaction in the surface molecular packing motifs of a fused thiophene derivative†

Xuan-Yun Wang,ab   Wei Jiang,a   Ting Chen,a   Hui-Juan Yan,a   Zhao-Hui Wang,a   Li-Jun Wana  and  Dong Wang*a  

* Corresponding authors

a Institute of Chemistry, Chinese Academy of Sciences, Beijing National Laboratory for Molecular Sciences, Beijing 100190, People's Republic of China
E-mail: wangd@iccas.ac.cn
Fax: +86-10-82616935
Tel: +86-10-82616935

b University of Chinese Academy of Sciences, Beijing, People's Republic of China

Abstract

A microscopic investigation of the molecular packing structures of a fused thiophene derivative reveals the important role of intermolecular S⋯S interaction in directing the 2D self-assembly. Thermal annealing of the assembly results in the irreversible phase transition to a new structure with different molecular trimeric packing motifs.

Graphical abstract: Molecular evidence for the intermolecular S⋯S interaction in the surface molecular packing motifs of a fused thiophene derivative

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Article information

DOI
https://doi.org/10.1039/C3CC37990F
Article type
Communication
Submitted
05 Nov 2012
Accepted
16 Jan 2013
First published
17 Jan 2013

Chem. Commun., 2013,49, 1829-1831

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Molecular evidence for the intermolecular S⋯S interaction in the surface molecular packing motifs of a fused thiophene derivative

X. Wang, W. Jiang, T. Chen, H. Yan, Z. Wang, L. Wan and D. Wang, Chem. Commun., 2013, 49, 1829 DOI: 10.1039/C3CC37990F

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