Enhancement of CO2 selectivity in a pillared pcu MOM platform through pillar substitution

Patrick Nugent; Vanessah Rhodus; Tony Pham; Brant Tudor; Katherine Forrest; Lukasz Wojtas; Brian Space; Michael Zaworotko

doi:10.1039/C3CC37695H

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Enhancement of CO₂ selectivity in a pillared pcu MOM platform through pillar substitution†

Patrick Nugent,^a Vanessah Rhodus,^a Tony Pham,^a Brant Tudor,^a Katherine Forrest,^a Lukasz Wojtas,^a Brian Space^a and Michael Zaworotko*^a

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* Corresponding authors

^a Department of Chemistry, University of South Florida, 4202 East Fowler Avenue, CHE205, Tampa, FL 33620, USA
E-mail: xtal@usf.edu
Fax: +1 813 974 3203
Tel: +1 813 974 3451

Abstract

Pillar substitution in a long-known metal–organic material with saturated metal centres, [Cu(bipy)₂(SiF₆)]_n, has afforded the first crystallographically characterized porous materials based upon TiF₆²⁻ and SnF₆²⁻ anions as pillars. Gas adsorption studies revealed similar surface areas and adsorption isotherms but enhanced selectivity towards CO₂vs. CH₄ and N₂.

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Article information

DOI: https://doi.org/10.1039/C3CC37695H
Article type: Communication
Submitted: 22 Oct 2012
Accepted: 08 Jan 2013
First published: 09 Jan 2013

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Chem. Commun., 2013,49, 1606-1608

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Enhancement of CO₂ selectivity in a pillared pcu MOM platform through pillar substitution

P. Nugent, V. Rhodus, T. Pham, B. Tudor, K. Forrest, L. Wojtas, B. Space and M. Zaworotko, Chem. Commun., 2013, 49, 1606 DOI: 10.1039/C3CC37695H

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Chemical Communications