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Issue 61, 2013
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A PdAg bimetallic nanocatalyst for selective reductive amination of nitroarenes

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Abstract

Herein we have identified an optimal catalyst, Pd1Ag1.7, for the tandem reductive amination between nitroarenes and aldehydes (selectivity > 93%). Key to the success is the ability to control the compositions of the investigational Pd1−xAgx (x = 0–1) catalysts, as well as the clear composition dependent activity/selectivity trend observed in this study. This catalyst features a wide substrate scope, excellent recyclability, activity and selectivity under ambient conditions.

Graphical abstract: A PdAg bimetallic nanocatalyst for selective reductive amination of nitroarenes

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Publication details

The article was received on 11 Jan 2013, accepted on 28 Feb 2013 and first published on 07 Mar 2013


Article type: Communication
DOI: 10.1039/C3CC00249G
Citation: Chem. Commun., 2013,49, 6843-6845
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    A PdAg bimetallic nanocatalyst for selective reductive amination of nitroarenes

    L. Li, Z. Niu, S. Cai, Y. Zhi, H. Li, H. Rong, L. Liu, L. Liu, W. He and Y. Li, Chem. Commun., 2013, 49, 6843
    DOI: 10.1039/C3CC00249G

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