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Issue 29, 2013
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Chiral aryl iodide catalysts for the enantioselective synthesis of para-quinols

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Abstract

Molecular modelling of an iodine(III) phenoxide was used as a starting point in the design of chiral aryl iodide catalysts for stereoselective oxidative dearomatization reactions. Using this approach, catalysts derived from 8-iodotetralone and tartaric acid were constructed and used to synthesize enantioenriched para-quinols from phenols.

Graphical abstract: Chiral aryl iodide catalysts for the enantioselective synthesis of para-quinols

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Publication details

The article was received on 01 Jan 2013, accepted on 25 Feb 2013 and first published on 26 Feb 2013


Article type: Communication
DOI: 10.1039/C3CC00013C
Citation: Chem. Commun., 2013,49, 3001-3003
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    Chiral aryl iodide catalysts for the enantioselective synthesis of para-quinols

    K. A. Volp and A. M. Harned, Chem. Commun., 2013, 49, 3001
    DOI: 10.1039/C3CC00013C

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