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Issue 31, 2013
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Stable ruthenium indenylidene complexes with a sterically reduced NHC ligand

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Abstract

Stable and active Ru olefin metathesis catalyst 7 bearing a sterically reduced NHC ligand was synthesized. Upon action of pyridine, 7 forms complex 24, the first example of an Ru–indenylidene catalyst bearing a labile pyridine ligand and a sterically less demanding NHC ligand.

Graphical abstract: Stable ruthenium indenylidene complexes with a sterically reduced NHC ligand

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Publication details

The article was received on 15 Oct 2012, accepted on 06 Dec 2012 and first published on 04 Jan 2013


Article type: Communication
DOI: 10.1039/C2CC37514A
Citation: Chem. Commun., 2013,49, 3188-3190
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    Stable ruthenium indenylidene complexes with a sterically reduced NHC ligand

    C. Torborg, G. Szczepaniak, A. Zieliński, M. Malińska, K. Woźniak and K. Grela, Chem. Commun., 2013, 49, 3188
    DOI: 10.1039/C2CC37514A

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