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Issue 35, 2014
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Ligand-controlled E/Z selectivity and enantioselectivity in palladium-catalyzed allylation of benzofuranones with 1,2-disubstituted allylic carbonates

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Abstract

The first highly E- and enantioselective allylic alkylation of prochiral carbon nucleophiles with 1,2-disubstituted allylic carbonates is reported. The key to the successful development of this protocol is the ability of modular ion-paired chiral ligands to simultaneously control the E/Z selectivity and enantioselectivity.

Graphical abstract: Ligand-controlled E/Z selectivity and enantioselectivity in palladium-catalyzed allylation of benzofuranones with 1,2-disubstituted allylic carbonates

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Publication details

The article was received on 09 Dec 2013, accepted on 19 Dec 2013 and first published on 23 Dec 2013


Article type: Communication
DOI: 10.1039/C3CC49338E
Citation: Chem. Commun., 2014,50, 4554-4557
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    Ligand-controlled E/Z selectivity and enantioselectivity in palladium-catalyzed allylation of benzofuranones with 1,2-disubstituted allylic carbonates

    K. Ohmatsu, M. Ito and T. Ooi, Chem. Commun., 2014, 50, 4554
    DOI: 10.1039/C3CC49338E

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