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Issue 24, 2014
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Tunable acid-sensitive ester protecting groups in oligosaccharide synthesis

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Abstract

A series of acid-cleavable ester-type protecting groups, with acid-sensitivity profiles parallel to those of 2-naphthylmethyl (NAP) or p-methoxybenzyl (PMB) ether, were designed and TFA in toluene was identified as a technically simple and effective deblocking cocktail for their global removal in the context of oligosaccharide synthesis.

Graphical abstract: Tunable acid-sensitive ester protecting groups in oligosaccharide synthesis

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Publication details

The article was received on 03 Dec 2013, accepted on 20 Dec 2013 and first published on 23 Dec 2013


Article type: Communication
DOI: 10.1039/C3CC49205B
Citation: Chem. Commun., 2014,50, 3155-3158
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    Tunable acid-sensitive ester protecting groups in oligosaccharide synthesis

    Y. Li and X. Liu, Chem. Commun., 2014, 50, 3155
    DOI: 10.1039/C3CC49205B

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