Issue 17, 2014
From the journal:

Chemical Communications

Palladium-catalyzed P(O)R2 directed C–H arylation to synthesize electron-rich polyaromatic monophosphorus ligands†

Rong-Bin Hu,a   Heng Zhang,a   Xiao-Yu Zhanga  and  Shang-Dong Yang*ab  

* Corresponding authors

a State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China
E-mail: yangshd@lzu.edu.cn
Fax: +86-931-8912859
Tel: +86-931-8912859

b State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Lanzhou 730000, P. R. China

Abstract

Palladium-catalyzed arylation of (diisopropylphosphoryl)biphenyl skeleton derivatives by the P(O)R2 directed C–H functionalization was reported. The related products were obtained in high regioselectivity and good functional group tolerance was observed. This reaction provided a new and efficient pathway for the synthesis of polyaromatic monophosphorus ligands.

Graphical abstract: Palladium-catalyzed P(O)R2 directed C–H arylation to synthesize electron-rich polyaromatic monophosphorus ligands

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Article information

DOI
https://doi.org/10.1039/C3CC49050E
Article type
Communication
Submitted
27 Nov 2013
Accepted
19 Dec 2013
First published
23 Dec 2013

Chem. Commun., 2014,50, 2193-2195

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Palladium-catalyzed P(O)R2 directed C–H arylation to synthesize electron-rich polyaromatic monophosphorus ligands

R. Hu, H. Zhang, X. Zhang and S. Yang, Chem. Commun., 2014, 50, 2193 DOI: 10.1039/C3CC49050E

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