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Issue 16, 2014
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An unexpected stereoisomerism in enantiomerically pure trisadducts of C60 with an inherently chiral trans-3,trans-3,trans-3 addition pattern

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Abstract

We have synthesized and isolated two C2-symmetric enantiomerically pure trisadducts of C60 with an inherently chiral trans-3,trans-3,trans-3 addition pattern with the aid of an enantiopure cyclo-tris-malonate tether. An unexpected stereoisomerism was observed which was attributed to the spatial arrangement of spacers in the tether.

Graphical abstract: An unexpected stereoisomerism in enantiomerically pure trisadducts of C60 with an inherently chiral trans-3,trans-3,trans-3 addition pattern

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Publication details

The article was received on 22 Nov 2013, accepted on 23 Dec 2013 and first published on 02 Jan 2014


Article type: Communication
DOI: 10.1039/C3CC48941H
Citation: Chem. Commun., 2014,50, 1995-1998
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    An unexpected stereoisomerism in enantiomerically pure trisadducts of C60 with an inherently chiral trans-3,trans-3,trans-3 addition pattern

    M. Riala and N. Chronakis, Chem. Commun., 2014, 50, 1995
    DOI: 10.1039/C3CC48941H

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