An unexpected stereoisomerism in enantiomerically pure trisadducts of C60 with an inherently chiral trans-3,trans-3,trans-3 addition pattern

Maria Riala; Nikos Chronakis

doi:10.1039/C3CC48941H

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An unexpected stereoisomerism in enantiomerically pure trisadducts of C₆₀ with an inherently chiral trans-3,trans-3,trans-3 addition pattern†

Maria Riala^a and Nikos Chronakis*^a

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* Corresponding authors

^a Department of Chemistry, University of Cyprus, University str. 1, Building No. 13, 2109 Aglantzia, Nicosia, Cyprus
E-mail: nchronak@ucy.ac.cy
Fax: +357 22895088
Tel: +357 22892781

Abstract

We have synthesized and isolated two C₂-symmetric enantiomerically pure trisadducts of C₆₀ with an inherently chiral trans-3,trans-3,trans-3 addition pattern with the aid of an enantiopure cyclo-tris-malonate tether. An unexpected stereoisomerism was observed which was attributed to the spatial arrangement of spacers in the tether.

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Article information

DOI: https://doi.org/10.1039/C3CC48941H
Article type: Communication
Submitted: 22 Nov 2013
Accepted: 23 Dec 2013
First published: 02 Jan 2014

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Chem. Commun., 2014,50, 1995-1998

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An unexpected stereoisomerism in enantiomerically pure trisadducts of C₆₀ with an inherently chiral trans-3,trans-3,trans-3 addition pattern

M. Riala and N. Chronakis, Chem. Commun., 2014, 50, 1995 DOI: 10.1039/C3CC48941H

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