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Issue 10, 2014
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Reaction of L2Zn2 with Ph2E2 – synthesis of LZnEPh and reactions with oxygen and H-acidic substrates

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Abstract

L2Zn2 (L = HC[C(Me)N(2,4,6-Me3C6H2)]2) and Ph2E2 (E = Se, Te) react to form LZnSePh (1) and LZnTePh (2). 1 and 2 further react with H2O and EtOH to form LZnOH (3) and LZnOEt (4), respectively, whereas the reaction of 2 with oxygen yielded [LZnOTe(O)Ph]2 (5). 1, 4 and 5 were characterized by single crystal X-ray diffraction.

Graphical abstract: Reaction of L2Zn2 with Ph2E2 – synthesis of LZnEPh and reactions with oxygen and H-acidic substrates

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The article was received on 13 Nov 2013, accepted on 15 Nov 2013 and first published on 18 Nov 2013


Article type: Communication
DOI: 10.1039/C3CC48677J
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 1189-1191
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    Reaction of L2Zn2 with Ph2E2 – synthesis of LZnEPh and reactions with oxygen and H-acidic substrates

    S. Gondzik, S. Schulz, D. Bläser and C. Wölper, Chem. Commun., 2014, 50, 1189
    DOI: 10.1039/C3CC48677J

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