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Issue 12, 2014
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Supramolecular assembly in a Janus-type urea system

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Abstract

A pyrazolyl urea ligand adopts two possible conformations with the urea NH groups directed either outward or inward. Metal coordination enforces the outward conformation resulting in either anion complexation or self-association and hence extended supramolecular assemblies including a hexameric barrel that persists in solution.

Graphical abstract: Supramolecular assembly in a Janus-type urea system

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Publication details

The article was received on 11 Nov 2013, accepted on 07 Dec 2013, published on 10 Dec 2013 and first published online on 10 Dec 2013


Article type: Communication
DOI: 10.1039/C3CC48603F
Citation: Chem. Commun., 2014,50, 1426-1428
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    Supramolecular assembly in a Janus-type urea system

    G. O. Lloyd and J. W. Steed, Chem. Commun., 2014, 50, 1426
    DOI: 10.1039/C3CC48603F

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