Jump to main content
Jump to site search

Issue 17, 2014
Previous Article Next Article

Regioselective synthesis of 2,3-dihydrobenzodioxepinones from epoxides and 2-bromophenols via palladium-catalyzed carbonylation

Author affiliations

Abstract

A highly regioselective cascade synthesis of 2,3-dihydrobenzodioxepinone from 2-bromophenols and epoxides has been developed. The reactions go through nucleophilic ring-opening of epoxides and subsequent palladium-catalyzed intramolecular alkoxylcarbonylation.

Graphical abstract: Regioselective synthesis of 2,3-dihydrobenzodioxepinones from epoxides and 2-bromophenols via palladium-catalyzed carbonylation

Back to tab navigation

Supplementary files

Publication details

The article was received on 06 Nov 2013, accepted on 19 Dec 2013 and first published on 23 Dec 2013


Article type: Communication
DOI: 10.1039/C3CC48490D
Citation: Chem. Commun., 2014,50, 2114-2116
  •   Request permissions

    Regioselective synthesis of 2,3-dihydrobenzodioxepinones from epoxides and 2-bromophenols via palladium-catalyzed carbonylation

    H. Li, A. Spannenberg, H. Neumann, M. Beller and X. Wu, Chem. Commun., 2014, 50, 2114
    DOI: 10.1039/C3CC48490D

Search articles by author

Spotlight

Advertisements