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Issue 15, 2014
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Immobilisation of photoswitchable diarylcyclohexenes synthesised via cobalt-mediated Diels–Alder reaction

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Abstract

Functionalised photoswitches – photochromic dithienylcyclohexenes – were prepared in two steps by a cobalt-mediated Diels–Alder reaction of internal alkynes with the isoprenylpinacolboronic ester. The three-component one-pot reaction sequence provides the photochromic dithienylcyclohexenes in up to 67% overall yield.

Graphical abstract: Immobilisation of photoswitchable diarylcyclohexenes synthesised via cobalt-mediated Diels–Alder reaction

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Publication details

The article was received on 06 Nov 2013, accepted on 20 Dec 2013 and first published on 23 Dec 2013


Article type: Communication
DOI: 10.1039/C3CC48487D
Citation: Chem. Commun., 2014,50, 1864-1866
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    Immobilisation of photoswitchable diarylcyclohexenes synthesised via cobalt-mediated Diels–Alder reaction

    P. Raster, A. Schmidt, M. Rambow, N. Kuzmanovic, B. König and G. Hilt, Chem. Commun., 2014, 50, 1864
    DOI: 10.1039/C3CC48487D

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