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Issue 9, 2014
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Vapochemically and mechanochemically reversible polymerization/depolymerization of S–Fe–Cu carbonyl clusters

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Abstract

A reversible vapochemical and mechanochemical solid-state transformation between a dppe-linked SFe3Cu2-based cluster [{(μ3-S)Fe3(CO)9}Cu2(dppe)] (2) and its 1D polymer [{(μ4-S)Fe3(CO)9}Cu2(dppe)(MeCN)2]n (3) was demonstrated, in which polymer 3 exhibited semi-conducting properties with an energy gap of 1.69 eV.

Graphical abstract: Vapochemically and mechanochemically reversible polymerization/depolymerization of S–Fe–Cu carbonyl clusters

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Publication details

The article was received on 30 Oct 2013, accepted on 18 Nov 2013 and first published on 25 Nov 2013


Article type: Communication
DOI: 10.1039/C3CC48303G
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 1134-1136
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    Vapochemically and mechanochemically reversible polymerization/depolymerization of S–Fe–Cu carbonyl clusters

    C. Lin, W. Jhu and M. Shieh, Chem. Commun., 2014, 50, 1134
    DOI: 10.1039/C3CC48303G

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