Issue 9, 2014
From the journal:

Chemical Communications

Vapochemically and mechanochemically reversible polymerization/depolymerization of S–Fe–Cu carbonyl clusters†

Chien-Nan Lin,a   Wei-Ting Jhua  and  Minghuey Shieh*a  

* Corresponding authors

a Department of Chemistry, National Taiwan Normal University, 88, Sec. 4, Tingchow Road, Taipei 11677, Taiwan, Republic of China
E-mail: mshieh@ntnu.edu.tw
Fax: +886-2-29309081
Tel: +886-2-77346118

Abstract

A reversible vapochemical and mechanochemical solid-state transformation between a dppe-linked SFe3Cu2-based cluster [{(μ3-S)Fe3(CO)9}Cu2(dppe)] (2) and its 1D polymer [{(μ4-S)Fe3(CO)9}Cu2(dppe)(MeCN)2]n (3) was demonstrated, in which polymer 3 exhibited semi-conducting properties with an energy gap of 1.69 eV.

Graphical abstract: Vapochemically and mechanochemically reversible polymerization/depolymerization of S–Fe–Cu carbonyl clusters

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Article information

DOI
https://doi.org/10.1039/C3CC48303G
Article type
Communication
Submitted
30 Oct 2013
Accepted
18 Nov 2013
First published
25 Nov 2013

Chem. Commun., 2014,50, 1134-1136

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Vapochemically and mechanochemically reversible polymerization/depolymerization of S–Fe–Cu carbonyl clusters

C. Lin, W. Jhu and M. Shieh, Chem. Commun., 2014, 50, 1134 DOI: 10.1039/C3CC48303G

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