Jump to main content
Jump to site search

Issue 9, 2014
Previous Article Next Article

Kinetic stabilization against the oxidation reaction induced by a silaalkane cage in a thiophene-bridged molecular gyroscope

Author affiliations

Abstract

Macrocage molecules with a bridged rotor have been synthesized as molecular gyroscopes. The kinetics of the oxidation reaction of the thiophene-bridged molecular gyroscope, whose thiophene ring was bridged inside a silaalkane cage, was investigated. A remarkable kinetic stabilization against the oxidation of the thiophene moiety induced by the molecular cage framework was observed.

Graphical abstract: Kinetic stabilization against the oxidation reaction induced by a silaalkane cage in a thiophene-bridged molecular gyroscope

Back to tab navigation

Supplementary files

Publication details

The article was received on 26 Oct 2013, accepted on 19 Nov 2013 and first published on 19 Nov 2013


Article type: Communication
DOI: 10.1039/C3CC48205G
Citation: Chem. Commun., 2014,50, 1098-1100
  •   Request permissions

    Kinetic stabilization against the oxidation reaction induced by a silaalkane cage in a thiophene-bridged molecular gyroscope

    W. Setaka, S. Ohmizu and M. Kira, Chem. Commun., 2014, 50, 1098
    DOI: 10.1039/C3CC48205G

Search articles by author

Spotlight

Advertisements