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Issue 7, 2014
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Organocatalyzed cascade reactions of carbohydrates – a direct access to C-glycosides

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Abstract

An organocatalyzed transformation to elongate unprotected carbohydrates is described. This operationally simple methodology is based on a Knoevenagel–oxa-Michael cascade. This reaction is catalyzed by proline and DBU. Products were obtained with exceptional high degrees of stereoselectivity.

Graphical abstract: Organocatalyzed cascade reactions of carbohydrates – a direct access to C-glycosides

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Publication details

The article was received on 23 Oct 2013, accepted on 13 Nov 2013 and first published on 13 Nov 2013


Article type: Communication
DOI: 10.1039/C3CC48120D
Citation: Chem. Commun., 2014,50, 817-819
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    Organocatalyzed cascade reactions of carbohydrates – a direct access to C-glycosides

    B. Voigt and R. Mahrwald, Chem. Commun., 2014, 50, 817
    DOI: 10.1039/C3CC48120D

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