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Issue 14, 2014
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Selective on/off switching at room temperature of a magnetic bistable {Fe2Co2} complex with single crystal-to-single crystal transformation via intramolecular electron transfer

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Abstract

A cyano-bridged {Fe2Co2} complex shows reversible single crystal-to-single crystal transformation between diamagnetic and paramagnetic states switched specifically by losing and absorbing methanol at room temperature in the solid state. And the solvent loss form presents temperature- and pressure-induced intramolecular electron transfer behaviour.

Graphical abstract: Selective on/off switching at room temperature of a magnetic bistable {Fe2Co2} complex with single crystal-to-single crystal transformation via intramolecular electron transfer

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Publication details

The article was received on 23 Oct 2013, accepted on 19 Nov 2013 and first published on 19 Nov 2013


Article type: Communication
DOI: 10.1039/C3CC48116F
Citation: Chem. Commun., 2014,50, 1665-1667
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    Selective on/off switching at room temperature of a magnetic bistable {Fe2Co2} complex with single crystal-to-single crystal transformation via intramolecular electron transfer

    L. Cao, J. Tao, Q. Gao, T. Liu, Z. Xia and D. Li, Chem. Commun., 2014, 50, 1665
    DOI: 10.1039/C3CC48116F

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