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Issue 10, 2014
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The effect of the size of surface Pd island ensembles on electron transfer of adsorbed perchlorate ions on Au(111)

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Abstract

A progressive increase in the size of Pd ensembles on a mica-supported Au(111) single crystal surface can facilitate electron transfer of perchlorate ions at lower anodic potential in CV curves than pure Au(111) due to a strong ligand effect and Pd–Au neighbouring pairs at edge sites render a higher degree of electron transfer.

Graphical abstract: The effect of the size of surface Pd island ensembles on electron transfer of adsorbed perchlorate ions on Au(111)

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Publication details

The article was received on 18 Oct 2013, accepted on 20 Nov 2013 and first published on 21 Nov 2013


Article type: Communication
DOI: 10.1039/C3CC48038K
Citation: Chem. Commun., 2014,50, 1198-1201
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    The effect of the size of surface Pd island ensembles on electron transfer of adsorbed perchlorate ions on Au(111)

    C. Wu, F. Xu, M. R. Castell and S. C. E. Tsang, Chem. Commun., 2014, 50, 1198
    DOI: 10.1039/C3CC48038K

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