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Issue 6, 2014
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Modulation of breathing behavior of layered coordination polymers via a solid solution approach: the influence of metal ions on sorption behavior

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Abstract

Four iso-structural layered coordination polymers (CPs) of Cd(II) and Zn(II) were shown to exhibit breathing transitions with N2/H2 gases. Furthermore, the solid solutions containing Zn(II)/Cd(II) have shown better uptake capacities of gas than parent CPs. These results give some insights into the role of metal ions and anions for fine-tuning the porosity of CPs.

Graphical abstract: Modulation of breathing behavior of layered coordination polymers via a solid solution approach: the influence of metal ions on sorption behavior

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Publication details

The article was received on 18 Oct 2013, accepted on 31 Oct 2013 and first published on 01 Nov 2013


Article type: Communication
DOI: 10.1039/C3CC48020H
Citation: Chem. Commun., 2014,50, 670-672
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    Modulation of breathing behavior of layered coordination polymers via a solid solution approach: the influence of metal ions on sorption behavior

    G. Mukherjee and K. Biradha, Chem. Commun., 2014, 50, 670
    DOI: 10.1039/C3CC48020H

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