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Issue 40, 2014
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Pyridine-2-thiolate bridged tin–palladium complexes with Sn(PdN2Cl2), Sn(PdN2S2), Sn(PdN2C2) and Sn(Pd2N4) skeletons

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Abstract

Reactions of tin(IV) complexes of the type Sn(PyS)2X2 (X = Cl, PyS, Ph; PyS = pyridine-2-thiolate) with Pd(PPh3)4 provide easy access to novel heterometallic complexes with Pd–Sn bonds. Electronic characteristics of this connection were analysed by X-ray crystallography, 119Sn Mössbauer spectroscopy and quantum chemical analyses.

Graphical abstract: Pyridine-2-thiolate bridged tin–palladium complexes with Sn(PdN2Cl2), Sn(PdN2S2), Sn(PdN2C2) and Sn(Pd2N4) skeletons

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Publication details

The article was received on 16 Oct 2013, accepted on 02 Dec 2013 and first published on 03 Dec 2013


Article type: Communication
DOI: 10.1039/C3CC47912A
Citation: Chem. Commun., 2014,50, 5382-5384
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    Pyridine-2-thiolate bridged tin–palladium complexes with Sn(PdN2Cl2), Sn(PdN2S2), Sn(PdN2C2) and Sn(Pd2N4) skeletons

    E. Wächtler, R. Gericke, L. Zhechkov, T. Heine, T. Langer, B. Gerke, R. Pöttgen and J. Wagler, Chem. Commun., 2014, 50, 5382
    DOI: 10.1039/C3CC47912A

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