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Issue 9, 2014
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Ruthenium-catalyzed ortho-C–H halogenations of benzamides

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Abstract

[Ru3(CO)12] and AgO2C(1-Ad) enabled the first ruthenium-catalyzed intermolecular halogenations of arenes via C–H activation. Thereby, brominations and iodinations of electron-rich and electron-deficient benzamides were achieved in a highly selective fashion.

Graphical abstract: Ruthenium-catalyzed ortho-C–H halogenations of benzamides

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Publication details

The article was received on 12 Oct 2013, accepted on 22 Nov 2013 and first published on 22 Nov 2013


Article type: Communication
DOI: 10.1039/C3CC47852A
Citation: Chem. Commun., 2014,50, 1083-1085
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    Ruthenium-catalyzed ortho-C–H halogenations of benzamides

    L. Wang and L. Ackermann, Chem. Commun., 2014, 50, 1083
    DOI: 10.1039/C3CC47852A

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