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Issue 14, 2014
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One pot synthesis of cyclohexanone oxime from nitrobenzene using a bifunctional catalyst

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Abstract

Cyclohexanone oxime is formed from nitrobenzene with 97% yield in a one-pot reaction catalysed by palladium and gold nanoparticles on carbon. The reaction is carried out under hydrogen at 60 °C and the overall transformation involves a multi-step catalysed mechanism from which intermediates and catalytically active species have been identified.

Graphical abstract: One pot synthesis of cyclohexanone oxime from nitrobenzene using a bifunctional catalyst

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Publication details

The article was received on 07 Oct 2013, accepted on 04 Nov 2013 and first published on 05 Nov 2013


Article type: Communication
DOI: 10.1039/C3CC47693F
Citation: Chem. Commun., 2014,50, 1645-1647
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    One pot synthesis of cyclohexanone oxime from nitrobenzene using a bifunctional catalyst

    P. Rubio-Marqués, J. C. Hernández-Garrido, A. Leyva-Pérez and A. Corma, Chem. Commun., 2014, 50, 1645
    DOI: 10.1039/C3CC47693F

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