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Issue 7, 2014
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Thermally/hydrolytically stable covalent organic frameworks from a rigid macrocyclic host

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Abstract

Two new 2D COFs were synthesized from triformylcyclotrianisylene, which show not only thermal stability but also hydrolytic stability. CTV-COF-1 with smaller pore size stored a high hydrogen level of 1.3 wt% at low pressure, while CTV-COF-2 with larger pore size showed superior carbon dioxide uptake, up to 250 cm3 gāˆ’1 at 298 K and 50 bar.

Graphical abstract: Thermally/hydrolytically stable covalent organic frameworks from a rigid macrocyclic host

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Publication details

The article was received on 05 Oct 2013, accepted on 24 Oct 2013 and first published on 24 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC47652A
Citation: Chem. Commun., 2014,50, 788-791
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    Thermally/hydrolytically stable covalent organic frameworks from a rigid macrocyclic host

    J. Song, J. Sun, J. Liu, Z. Huang and Q. Zheng, Chem. Commun., 2014, 50, 788
    DOI: 10.1039/C3CC47652A

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