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Issue 1, 2014
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Enantioselective desymmetrization of prochiral 1,3-dinitropropanes via organocatalytic allylic alkylation

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Abstract

An enantioselective desymmetrization of prochiral 1,3-dinitropropanes has been developed which proceeds via enantiogroup differentiating organocatalytic allylic alkylation. Densely functionalized products with two vicinal stereocenters were obtained generally with good to excellent diastereoselectivity (up to >20 : 1 dr) and superb enantioselectivity (up to >99 : 1 er).

Graphical abstract: Enantioselective desymmetrization of prochiral 1,3-dinitropropanes via organocatalytic allylic alkylation

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Publication details

The article was received on 05 Oct 2013, accepted on 23 Oct 2013 and first published on 23 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC47645F
Citation: Chem. Commun., 2014,50, 121-123
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    Enantioselective desymmetrization of prochiral 1,3-dinitropropanes via organocatalytic allylic alkylation

    S. J. Singha Roy and S. Mukherjee, Chem. Commun., 2014, 50, 121
    DOI: 10.1039/C3CC47645F

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