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A copper-mediated tandem reaction through isocyanide insertion into N–H bonds: efficient access to unsymmetrical tetrasubstituted ureas

Xiaomei Huang,a   Shuguang Xu,a   Qitao Tan,a   Mingchun Gao,a   Minjie Lia and   Bin Xu*abc  
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a
Department of Chemistry, Shanghai University, Shanghai 200444, P. R. China
E-mail: xubin@shu.edu.cn;
Fax: +86-21-66132830 ;
Tel: +86-21-66132830
b
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, P. R. China
c
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, China
Chem. Commun., 2014,50, 1465-1468

DOI: 10.1039/C3CC47590E
Received 03 Oct 2013, Accepted 26 Nov 2013
First published online 27 Nov 2013
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