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Issue 9, 2014
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Recent advances in cooperative bimetallic asymmetric catalysis: dinuclear Schiff base complexes

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Abstract

Cooperative catalysis has proven to be a powerful strategy for realizing high reactivity and selectivity in asymmetric transformations. A variety of cooperative asymmetric catalysts have been developed over the last two decades. In this feature article, recent advances from our research on cooperative asymmetric catalysis, focusing on dinuclear Schiff base catalysis, are described. Design of dinuclear Schiff base catalysts and their applications in several asymmetric C–C and C–N bond-forming reactions under simple proton transfer conditions with perfect atom-economy are discussed in detail.

Graphical abstract: Recent advances in cooperative bimetallic asymmetric catalysis: dinuclear Schiff base complexes

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Publication details

The article was received on 03 Oct 2013, accepted on 04 Nov 2013 and first published on 05 Nov 2013


Article type: Feature Article
DOI: 10.1039/C3CC47587E
Citation: Chem. Commun., 2014,50, 1044-1057
  • Open access: Creative Commons BY license
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    Recent advances in cooperative bimetallic asymmetric catalysis: dinuclear Schiff base complexes

    S. Matsunaga and M. Shibasaki, Chem. Commun., 2014, 50, 1044
    DOI: 10.1039/C3CC47587E

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