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Issue 98, 2013
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Design of aromatic heteropolycyclics containing borole frameworks

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Abstract

The heteropolycyclic compounds containing borole units were theoretically designed. The presence of electron deficient boron atoms results in full electron delocalization and remarkably affects their aromaticity. While molecules 1 and 2a exhibit antiaromaticity for inner rings and non-aromaticity for outer rings, 2b and 2c are completely aromatic.

Graphical abstract: Design of aromatic heteropolycyclics containing borole frameworks

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Publication details

The article was received on 04 Oct 2013, accepted on 16 Oct 2013 and first published on 17 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC47573E
Citation: Chem. Commun., 2013,49, 11548-11550
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    Design of aromatic heteropolycyclics containing borole frameworks

    T. B. Tai, V. T. T. Huong and M. T. Nguyen, Chem. Commun., 2013, 49, 11548
    DOI: 10.1039/C3CC47573E

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