Issue 98, 2013
From the journal:

Chemical Communications

Design of aromatic heteropolycyclics containing borole frameworks†

Truong Ba Tai,*a   Vu Thi Thu Huonga  and  Minh Tho Nguyen*a  

* Corresponding authors

a Department of Chemistry, University of Leuven, Celestijnenlaan 200F, Leuven, Belgium
E-mail: truong.batai@chem.kuleuven.be, minh.nguyen@chem.kuleuven.be

Abstract

The heteropolycyclic compounds containing borole units were theoretically designed. The presence of electron deficient boron atoms results in full electron delocalization and remarkably affects their aromaticity. While molecules 1 and 2a exhibit antiaromaticity for inner rings and non-aromaticity for outer rings, 2b and 2c are completely aromatic.

Graphical abstract: Design of aromatic heteropolycyclics containing borole frameworks

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Article information

DOI
https://doi.org/10.1039/C3CC47573E
Article type
Communication
Submitted
04 Oct 2013
Accepted
16 Oct 2013
First published
17 Oct 2013

Chem. Commun., 2013,49, 11548-11550

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Design of aromatic heteropolycyclics containing borole frameworks

T. B. Tai, V. T. T. Huong and M. T. Nguyen, Chem. Commun., 2013, 49, 11548 DOI: 10.1039/C3CC47573E

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