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Issue 100, 2013
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Desymmetrization of cyclic olefins via asymmetric Heck reaction and hydroarylation

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Abstract

An asymmetric Heck reaction allows desymmetrization of substituted cyclic olefins in high dr and ee. A bisphosphine oxide is uniquely stereoselective for this purpose. Desymmetrization of bicyclic olefins via hydroarylation can also be realized in high ee.

Graphical abstract: Desymmetrization of cyclic olefins via asymmetric Heck reaction and hydroarylation

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Publication details

The article was received on 02 Oct 2013, accepted on 22 Oct 2013 and first published on 22 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC47551D
Citation: Chem. Commun., 2013,49, 11758-11760
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    Desymmetrization of cyclic olefins via asymmetric Heck reaction and hydroarylation

    S. Liu and J. (. Zhou, Chem. Commun., 2013, 49, 11758
    DOI: 10.1039/C3CC47551D

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