Issue 100, 2013
From the journal:

Chemical Communications

Desymmetrization of cyclic olefins via asymmetric Heck reaction and hydroarylation†

Sijia Liua  and  Jianrong (Steve) Zhou*a  

* Corresponding authors

a Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore 637371, Singapore
E-mail: jrzhou@ntu.edu.sg
Fax: +65 67911961

Abstract

An asymmetric Heck reaction allows desymmetrization of substituted cyclic olefins in high dr and ee. A bisphosphine oxide is uniquely stereoselective for this purpose. Desymmetrization of bicyclic olefins via hydroarylation can also be realized in high ee.

Graphical abstract: Desymmetrization of cyclic olefins via asymmetric Heck reaction and hydroarylation

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Article information

DOI
https://doi.org/10.1039/C3CC47551D
Article type
Communication
Submitted
02 Oct 2013
Accepted
22 Oct 2013
First published
22 Oct 2013

Chem. Commun., 2013,49, 11758-11760

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Desymmetrization of cyclic olefins via asymmetric Heck reaction and hydroarylation

S. Liu and J. (. Zhou, Chem. Commun., 2013, 49, 11758 DOI: 10.1039/C3CC47551D

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