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Issue 40, 2014
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C–C bond migration in the cycloisomerization of oxygen-tethered 1,6-enynes

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Abstract

A C–C bond migration event during the cycloisomerization of 1,6-enynes is described. Two different catalytic systems, iridium- or platinum-based, are able to induce this process. Alkyl migrations of larger rings and acyclic groups indicate that the reaction is not fully driven by the release of ring strain.

Graphical abstract: C–C bond migration in the cycloisomerization of oxygen-tethered 1,6-enynes

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Publication details

The article was received on 30 Sep 2013, accepted on 26 Nov 2013 and first published on 27 Nov 2013


Article type: Communication
DOI: 10.1039/C3CC47499B
Citation: Chem. Commun., 2014,50, 5239-5241
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    C–C bond migration in the cycloisomerization of oxygen-tethered 1,6-enynes

    S. M. Stevenson, E. T. Newcomb and E. M. Ferreira, Chem. Commun., 2014, 50, 5239
    DOI: 10.1039/C3CC47499B

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