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Issue 3, 2014
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A novel aluminoborate open-framework [In(dien)2][Al2B7O16H2] with large chiral cavities templated by chiral main group metal complexes

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Abstract

A novel aluminoborate open-framework [In(dien)2][Al2B7O16H2] (1, dien = diethylenetriamine) with large chiral cavities has been constructed under solvothermal conditions, in which AlO4 and chainlike B4O8 units are alternately linked to form a network with 20-membered ring windows and then further joined by XO4 (X = 0.5 Al + 0.5 B) units to give a three-dimensional framework.

Graphical abstract: A novel aluminoborate open-framework [In(dien)2][Al2B7O16H2] with large chiral cavities templated by chiral main group metal complexes

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Publication details

The article was received on 29 Sep 2013, accepted on 30 Oct 2013 and first published on 30 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC47440B
Citation: Chem. Commun., 2014,50, 344-346
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    A novel aluminoborate open-framework [In(dien)2][Al2B7O16H2] with large chiral cavities templated by chiral main group metal complexes

    L. Cheng and G. Yang, Chem. Commun., 2014, 50, 344
    DOI: 10.1039/C3CC47440B

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