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Issue 2, 2014
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Synthesis of rotacatenanes by the combination of Cu-mediated threading reaction and the template method: the dual role of one ligand

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Abstract

Rotacatenanes were synthesized by the catalytic reaction using a macrocyclic phenanthroline–CuI complex followed by the installation of another ring by the template method. In this approach, the size of the ring component of the rotaxane turns out to be a very important factor for the synthesis of rotacatenanes.

Graphical abstract: Synthesis of rotacatenanes by the combination of Cu-mediated threading reaction and the template method: the dual role of one ligand

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Publication details

The article was received on 28 Sep 2013, accepted on 22 Oct 2013 and first published on 24 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC47425A
Citation: Chem. Commun., 2014,50, 204-206
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    Synthesis of rotacatenanes by the combination of Cu-mediated threading reaction and the template method: the dual role of one ligand

    R. Hayashi, K. Wakatsuki, R. Yamasaki, Y. Mutoh, T. Kasama and S. Saito, Chem. Commun., 2014, 50, 204
    DOI: 10.1039/C3CC47425A

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