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Issue 1, 2014
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A novel, rigid diphosphine with an active NHC spacer; di- and trinuclear complexes of d10 coinage metals

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Abstract

A novel N,N′-diphosphanyl-imidazol-2-ylidene acts as a stable, hybrid PCNHCP ligand for M2 or linear M3 (M = Cu, Ag, Au) arrays with metallophilic interactions.

Graphical abstract: A novel, rigid diphosphine with an active NHC spacer; di- and trinuclear complexes of d10 coinage metals

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Publication details

The article was received on 26 Sep 2013, accepted on 22 Oct 2013 and first published on 24 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC47370H
Citation: Chem. Commun., 2014,50, 103-105
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    A novel, rigid diphosphine with an active NHC spacer; di- and trinuclear complexes of d10 coinage metals

    P. Ai, A. A. Danopoulos, P. Braunstein and K. Yu. Monakhov, Chem. Commun., 2014, 50, 103
    DOI: 10.1039/C3CC47370H

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