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Issue 97, 2013
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Reduction-free synthesis of stable acetylide cobalamins

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Abstract

A straightforward, reduction-free method for the synthesis of organometallic cobalamins has been developed. Stable phenylacetylide derivatives were characterized by X-ray analysis, showing a pronounced influence of the electronic nature of substituents on their structure.

Graphical abstract: Reduction-free synthesis of stable acetylide cobalamins

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Publication details

The article was received on 20 Sep 2013, accepted on 09 Oct 2013 and first published on 14 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC47210H
Citation: Chem. Commun., 2013,49, 11406-11408
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    Reduction-free synthesis of stable acetylide cobalamins

    M. Chromiński, A. Lewalska and D. Gryko, Chem. Commun., 2013, 49, 11406
    DOI: 10.1039/C3CC47210H

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