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Issue 98, 2013
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Simple one-pot regioselective 6-O-phosphorylation of carbohydrates and trehalose desymmetrization

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Abstract

Biologically essential carbohydrate 6-phosphates, especially trehalose 6-phosphate, can be synthesized easily in excellent overall yields in 2 steps involving minimum protecting group manipulations. We can cleave the diphenylphosphate group for further synthetic objectives.

Graphical abstract: Simple one-pot regioselective 6-O-phosphorylation of carbohydrates and trehalose desymmetrization

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Publication details

The article was received on 19 Sep 2013, accepted on 16 Oct 2013 and first published on 17 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC47180B
Citation: Chem. Commun., 2013,49, 11497-11499
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    Simple one-pot regioselective 6-O-phosphorylation of carbohydrates and trehalose desymmetrization

    A. Abragam Joseph, C. Chang and C. Wang, Chem. Commun., 2013, 49, 11497
    DOI: 10.1039/C3CC47180B

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