Issue 3, 2014
From the journal:

Chemical Communications

Fluorescence probing of the ferric Fenton reaction via novel chelation†

Dhiraj P. Murale,a   Sudesh T. Manjare,ab   Yoon-Sup Leea  and  David G. Churchill*a  

* Corresponding authors

a Molecular Logic Gate Laboratory, Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), 373-1 Guseong-dong, Yuseong-gu, Daejeon, Republic of Korea
E-mail: dchurchill@kaist.ac.kr
Fax: +82-42-350-2810
Tel: +82-42-350-2845

b Center for Catalytic Hydrocarbon Functionalizations, Institute for Basic Science (IBS), 373-1 Guseong-dong, Yuseong-gu, Daejeon, Republic of Korea

Abstract

A new probe-chelator PET dyad was synthesised, which can be used to detect Fe3+via fluorescence enhancement to discriminate between Fe2+ and Fe3+via Fenton chemistry involving hydrogen peroxide. This is the first BODIPY which works as a 2 : 1 multiplexer for Fe3+, Fe2+ and H2O2.

Graphical abstract: Fluorescence probing of the ferric Fenton reaction via novel chelation

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Article information

DOI
https://doi.org/10.1039/C3CC47038E
Article type
Communication
Submitted
14 Sep 2013
Accepted
25 Oct 2013
First published
29 Oct 2013

Chem. Commun., 2014,50, 359-361

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Fluorescence probing of the ferric Fenton reaction via novel chelation

D. P. Murale, S. T. Manjare, Y. Lee and D. G. Churchill, Chem. Commun., 2014, 50, 359 DOI: 10.1039/C3CC47038E

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