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Issue 2, 2014
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A novel chiral yttrium complex with a tridentate linked amido-indenyl ligand for intramolecular hydroamination

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Abstract

A new chiral silicon-linked tridentate amido-indenyl ligand was developed from indene and enantiopure 1,2-cyclohexanediamine. Its yttrium complex was synthesized, characterized and applied to efficiently catalyze the intramolecular hydroamination of non-activated olefins with up to 97% ee.

Graphical abstract: A novel chiral yttrium complex with a tridentate linked amido-indenyl ligand for intramolecular hydroamination

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Publication details

The article was received on 13 Sep 2013, accepted on 22 Oct 2013 and first published on 22 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC47006G
Citation: Chem. Commun., 2014,50, 177-179
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    A novel chiral yttrium complex with a tridentate linked amido-indenyl ligand for intramolecular hydroamination

    Z. Chai, D. Hua, K. Li, J. Chu and G. Yang, Chem. Commun., 2014, 50, 177
    DOI: 10.1039/C3CC47006G

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