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Issue 95, 2013
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Preparation and reactivity of a dinitrogen-bridged dimolybdenum-tetrachloride complex

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Abstract

A dinitrogen-bridged dimolybdenum-tetrachloride complex is prepared and reduced with Super-Hydride (LiBHEt3) to afford the corresponding dimolybdenum-dinitrogen complex together with the formation of molecular dihydrogen. This reaction proceeds via the ligand exchange of the coordinated dihydrogen generated in situ with molecular dinitrogen.

Graphical abstract: Preparation and reactivity of a dinitrogen-bridged dimolybdenum-tetrachloride complex

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Publication details

The article was received on 11 Sep 2013, accepted on 08 Oct 2013 and first published on 23 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC46946H
Citation: Chem. Commun., 2013,49, 11215-11217
  • Open access: Creative Commons BY-NC license
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    Preparation and reactivity of a dinitrogen-bridged dimolybdenum-tetrachloride complex

    K. Arashiba, S. Kuriyama, K. Nakajima and Y. Nishibayashi, Chem. Commun., 2013, 49, 11215
    DOI: 10.1039/C3CC46946H

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