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Issue 7, 2014
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Supramolecular architecture, crystal structure and transport properties of the prototypal oxobenzene-bridged bisdithiazolyl radical conductor

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Abstract

Supramolecular CH⋯π interactions cause a ruffling of the otherwise coplanar ribbon-like arrays of radicals in the structure of the oxobenzene-bridged bisdithiazolyl 1a. The material displays a conductivity σ(300 K) = 6 × 10−3 S cm−1 (Eact = 0.16 eV) and orders antiferromagnetically below 4 K. At applied fields above 1 kOe the material displays metamagnetic behavior.

Graphical abstract: Supramolecular architecture, crystal structure and transport properties of the prototypal oxobenzene-bridged bisdithiazolyl radical conductor

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Publication details

The article was received on 02 Sep 2013, accepted on 25 Sep 2013 and first published on 14 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC46686H
Citation: Chem. Commun., 2014,50, 785-787
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    Supramolecular architecture, crystal structure and transport properties of the prototypal oxobenzene-bridged bisdithiazolyl radical conductor

    J. W. L. Wong, A. Mailman, S. M. Winter, C. M. Robertson, R. J. Holmberg, M. Murugesu, P. A. Dube and R. T. Oakley, Chem. Commun., 2014, 50, 785
    DOI: 10.1039/C3CC46686H

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