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Issue 98, 2013
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Suzuki–Miyaura cross-coupling of bulky anthracenyl carboxylates by using pincer nickel N-heterocyclic carbene complexes: an efficient protocol to access fluorescent anthracene derivatives

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Abstract

A series of fluorescent (hetero)-aryl substituted anthracene derivatives were readily accessible from the corresponding bulky anthracen-9-yl carboxylates via Suzuki–Miyaura cross-coupling reactions by using pincer nickel N-heterocyclic carbene complex 1 even at the catalyst loading as low as 0.1 mol% in the presence of catalytic amounts of PCy3.

Graphical abstract: Suzuki–Miyaura cross-coupling of bulky anthracenyl carboxylates by using pincer nickel N-heterocyclic carbene complexes: an efficient protocol to access fluorescent anthracene derivatives

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Publication details

The article was received on 31 Aug 2013, accepted on 15 Oct 2013 and first published on 17 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC46663A
Citation: Chem. Commun., 2013,49, 11539-11541
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    Suzuki–Miyaura cross-coupling of bulky anthracenyl carboxylates by using pincer nickel N-heterocyclic carbene complexes: an efficient protocol to access fluorescent anthracene derivatives

    M. Xu, X. Li, Z. Sun and T. Tu, Chem. Commun., 2013, 49, 11539
    DOI: 10.1039/C3CC46663A

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