School of Chemistry, University of Bristol, Cantocks Close, Bristol BS8 1TS, UK
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Universidad de La Laguna, Dpto. de Química-Física, Instituto de Materiales y Nanotecnología, Avda. Astrofísico Francisco Sánchez s/n, 38071 La Laguna, Spain
; Tel: +34 92 2318028
Chem. Commun., 2013,49, 10962-10964
27 Aug 2013,
11 Oct 2013
First published online
14 Oct 2013
The faradaic efficiency of CO2 electroreduction is significantly affected by the thickness of Pd nanoshells on Au cores. The ratio of hydrogen evolution to CO2 reduction was determined by differential electrochemical mass spectrometry. Decreasing the Pd shell thickness from 10 to 1 nm leads to a twofold increase in faradaic efficiency.
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