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Issue 94, 2013
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An efficient method for the Heck–Catellani reaction of aryl halides

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Abstract

We describe herein a new method that allows selective production of Catellani–Heck isomers from various aryl halides, including ones without ortho-groups. Under previous conditions, unhindered aryl halides were plagued with the formation of simple Heck isomers and multiple arylation and norbornene insertion. The use of a bulky PtBu3 ligand accelerates C–C reductive elimination from the key palladacycle.

Graphical abstract: An efficient method for the Heck–Catellani reaction of aryl halides

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Publication details

The article was received on 20 Aug 2013, accepted on 02 Oct 2013 and first published on 02 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC46381H
Citation: Chem. Commun., 2013,49, 11035-11037
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    An efficient method for the Heck–Catellani reaction of aryl halides

    X. Wu and J. (. Zhou, Chem. Commun., 2013, 49, 11035
    DOI: 10.1039/C3CC46381H

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