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Issue 92, 2013
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Bingel–Hirsch monoadducts of TiSc2N@Ih-C80versus Sc3N@Ih-C80: reactivity improvement via internal metal atom substitution

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Abstract

The first Bingel–Hirsch reaction of TiSc2N@Ih-C80 afforded two unconventional singly bonded monoadducts, revealing the dramatically improved reactivity compared to Sc3N@Ih-C80 and obvious change in the addition pattern.

Graphical abstract: Bingel–Hirsch monoadducts of TiSc2N@Ih-C80versus Sc3N@Ih-C80: reactivity improvement via internal metal atom substitution

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Publication details

The article was received on 16 Aug 2013, accepted on 29 Sep 2013, published on 30 Sep 2013 and first published online on 30 Sep 2013


Article type: Communication
DOI: 10.1039/C3CC46277C
Citation: Chem. Commun., 2013,49, 10844-10846
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    Bingel–Hirsch monoadducts of TiSc2N@Ih-C80versus Sc3N@Ih-C80: reactivity improvement via internal metal atom substitution

    S. Yang, C. Chen, X. Li, T. Wei, F. Liu and S. Wang, Chem. Commun., 2013, 49, 10844
    DOI: 10.1039/C3CC46277C

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