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Issue 90, 2013
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Intercalation of chiral molecules into layered metal–organic frameworks: a strategy to synthesize homochiral MOFs

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Abstract

Two homochiral SHG MOFs with remarkable layered architectures were prepared by intercalation of (S or R)-5-oxopyrrolidine-2-carboxylate into layered MOFs assembled from hydrogenated Schiff base L and Zn(II). This is a novel strategy to design and synthesize homochiral coordination polymers and potential nonlinear optical materials.

Graphical abstract: Intercalation of chiral molecules into layered metal–organic frameworks: a strategy to synthesize homochiral MOFs

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Publication details

The article was received on 15 Aug 2013, accepted on 18 Sep 2013 and first published on 19 Sep 2013


Article type: Communication
DOI: 10.1039/C3CC46230G
Citation: Chem. Commun., 2013,49, 10644-10646
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    Intercalation of chiral molecules into layered metal–organic frameworks: a strategy to synthesize homochiral MOFs

    Y. Wen, T. Sheng, S. Hu, X. Ma, C. Tan, Y. Wang, Z. Sun, Z. Xue and X. Wu, Chem. Commun., 2013, 49, 10644
    DOI: 10.1039/C3CC46230G

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