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Issue 90, 2013
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A C3v-symmetrical tribenzotriquinacene-based threefold N-heterocyclic carbene. Coordination to rhodium(I) and stereoelectronic properties

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Abstract

A novel tribenzotriquinacene-based tris-NHC has been obtained and coordinated to rhodium. The new ligand displays a unique rigid C3v symmetry. The electrochemical analysis of the tri-rhodium complex reveals that the three metals are essentially disconnected.

Graphical abstract: A C3v-symmetrical tribenzotriquinacene-based threefold N-heterocyclic carbene. Coordination to rhodium(i) and stereoelectronic properties

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Publication details

The article was received on 12 Aug 2013, accepted on 18 Sep 2013 and first published on 19 Sep 2013


Article type: Communication
DOI: 10.1039/C3CC46155F
Citation: Chem. Commun., 2013,49, 10572-10574
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    A C3v-symmetrical tribenzotriquinacene-based threefold N-heterocyclic carbene. Coordination to rhodium(I) and stereoelectronic properties

    C. Segarra, J. Linke, E. Mas-Marzá, D. Kuck and E. Peris, Chem. Commun., 2013, 49, 10572
    DOI: 10.1039/C3CC46155F

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