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Issue 83, 2013
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Water-controlled synthesis and single-crystal structural transformations of a cyanide-bridged W(IV)–Ni(II) molecular wheel complex and 3D networks

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Abstract

One cyanide-bridged W(IV)–Ni(II) wheel-like complex and two three-dimensional (3D) networks can be directly synthesized based on K4[W(CN)8] and [Ni(L)](ClO4)2 precursors by controlling the quantity of water in organic solvent. The water-controlled single-crystal structural transformations among these complexes are described.

Graphical abstract: Water-controlled synthesis and single-crystal structural transformations of a cyanide-bridged W(iv)–Ni(ii) molecular wheel complex and 3D networks

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Publication details

The article was received on 08 Aug 2013, accepted on 16 Aug 2013 and first published on 19 Aug 2013


Article type: Communication
DOI: 10.1039/C3CC46063K
Citation: Chem. Commun., 2013,49, 9582-9584
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    Water-controlled synthesis and single-crystal structural transformations of a cyanide-bridged W(IV)–Ni(II) molecular wheel complex and 3D networks

    D. Zhang, L. Zhang, G. Li and Z. Ni, Chem. Commun., 2013, 49, 9582
    DOI: 10.1039/C3CC46063K

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